Search results for "surface layer"
showing 10 items of 72 documents
Evaporation from soils of different texture covered by layers of water repellent and wettable soils
2020
Water repellent soils are able to channel water deep into the soil profile by fingered flow, minimising water storage in the water repellent top layer where water is most susceptible to evaporation. To date, the effect of water repellent or wettable surface layer on evaporation from wet sublayer has only been reported for coarse materials, and an increase in water repellency led to a greater delay in water evaporation. The objective of this study was to assess the effect of water repellent vs. wettable top layers with different thickness on water evaporation from coarse and fine texture subsoils that were pre-moistened. Clay loam soil samples were taken from Pinus pinaster woodland of Ciavo…
Mesopolysaccharides: The extracellular surface layer of visceral organs
2020
The mesothelium is a dynamic and specialized tissue layer that covers the somatic cavities (pleural, peritoneal, and pericardial) as well as the surface of the visceral organs such as the lung, heart, liver, bowel and tunica vaginalis testis. The potential therapeutic manipulation of visceral organs has been complicated by the carbohydrate surface layer—here, called the mesopolysaccharide (MPS)—that coats the outer layer of the mesothelium. The traditional understanding of MPS structure has relied upon fixation techniques known to degrade carbohydrates. The recent development of carbohydrate-preserving fixation for high resolution imaging techniques has provided an opportunity to re-examine…
The Effect of Electronic Properties of Anodized and Hard Anodized Ti and Ti6Al4V on Their Reactivity in Simulated Body Fluid
2022
The electronic properties of barrier and porous layers on Ti and Ti6Al4V were studied. Barrier anodic oxides grown to 40 V on Ti and on Ti6Al4V are both n-type semiconductors with a band gap of 3.3 eV and 3.4 eV respectively, in agreement with the formation of amorphous TiO2. Anodizing to 200 V at 20 mA cm−2 in calcium acetate and β-glycerol phosphate disodium pentahydrate leads to the formation of Ca and P containing porous films with a photoelectrochemical behaviour dependent on the metallic substrate. A band gap of 3.2 eV and the flat band potential of −0.5 V vs Ag/AgCl were measured for the porous oxide on Ti, while optical transitions at 2.15 eV and a significantly more positive flat b…
Gradient elasticity and nonstandard boundary conditions
2003
Abstract Gradient elasticity for a second gradient model is addressed within a suitable thermodynamic framework apt to account for nonlocality. The pertinent thermodynamic restrictions upon the gradient constitutive equations are derived, which are shown to include, besides the field (differential) stress–strain laws, a set of nonstandard boundary conditions. Consistently with the latter thermodynamic requirements, a surface layer with membrane stresses is envisioned in the strained body, which together with the above nonstandard boundary conditions make the body constitutively insulated (i.e. no long distance energy flows out of the boundary surface due to nonlocality). The total strain en…
Depth selective Mössbauer spectroscopy: Analysis and simulation of 6.4 keV and 14.4 keV spectra obtained from rocks at Gusev Crater, Mars, and layere…
2008
[1] The miniaturized Mossbauer spectrometer (MIMOS) II Mossbauer spectrometers on the Mars Exploration Rovers (MER) simultaneously obtained 6.4 keV and 14.4 keV Mossbauer spectra from rock and soil targets. Because photons with lower energy have a shallower penetration depth, 6.4 keV spectra contain more mineralogical information about the near-surface region of a sample than do 14.4 keV spectra. The influence of surface layers of varying composition and thickness on Mossbauer spectra was investigated by Monte Carlo simulation and by measurement using a copy of the MER MIMOS II instrument and samples with one or two layers of known thicknesses. Thin sections of minerals or metallic Fe foil …
Influence of the passive film properties and residual stresses on the micro-electrochemical behavior of duplex stainless steels
2010
In the present paper, the chemical composition of passive films formed on both phases of two types of duplex stainless steels (UNS S31803 and UNS S32304) is determined at the micro-scale using Auger electron spectroscopy (AES). Samples were either mechanically polished (down to diamond pastes) or electrochemically etched in acidic solutions. The micro-electrochemical behavior of samples was then determined in sodium chloride media by means of the electrochemical micro-cell technique (capillary diameters of 30 μm). The results obtained were analyzed considering the passive film chemical composition. Quantitative relationships between electrochemical parameters and the distribution of chromiu…
Systematic trends in (0 0 1) surface ab initio calculations of ABO 3 perovskites
2018
This work was supported by the Latvian Council of Science Grant No. 374/2012 and the Latvian National Research Program IMIS2. Many stimulating discussions with D. Vanderbilt, K.M. Rabe, M. Rohlfing, E. Heifets, J. Maier, G. Borstel and E.A. Kotomin are greatly acknowledged.
Model calculations for wetting transitions in polymer mixtures
1985
Partially compatible binary mixtures of linear flexible polymers are considered in the presence of a wall which preferentially adsorbs one component. Using a Flory-Huggins type mean field approach, it is shown that in typical cases at two-phase coexistence the wall is always « wet », i.e. coated with a macroscopically thick layer of the preferred phase, and the transition to the non wet state occurs at volume fractions of the order of 1/~N (where N is the chain length) at the coexistence curve. Both first and second order wetting transitions are found, and the variation of the surface layer thickness, surface excess energy and related quantities through the transition is studied. We discuss…
Low temperature plasma treatment of monomolecular Langmuir-Blodgett films
1993
Abstract The structure of the surface layer of materials is usually quite different from the bulk. Detailed information about the surface structure is often not available. This, together with the complex nature of low temperature plasma treatment, hinders the investigations of plasma chemical processes on solid surfaces. Monomolecular Langmuir-Blodgett (LB) structures offer a unique opportunity to prepare model surfaces with known thickness and molecular architecture. From the data obtained, the depth of the Ar plasma influence on solid organic surfaces was estimated to be about 400–1000 A depending on the nature of the surface layer. An oxygen plasma penetrates deeper with a penetration li…
Box 5: Surface Crystallography Terminology
2009
The crystalline nature of the surface differs from the bulk because atoms on the surface experience a different force field due to unterminated bonds, oxidation by adatoms etc. [1]. Free energy minimisation leads to reconstruction of the surface layer from the bulk by formation of dimers and displacement of atoms from their normal sites.